PEXIP is a distributed conferencing interworking platform/gateway. It doesn't support outbound SIP register as you'd end up having each PEXIP node registering, which in a lot of deployments could be 10s or 100s. In PEXIP registration is typically reserved for endpoints.
What PCAP is trying to do is route all calls to an extension, in this case 75000, out to a PEXIP node either via it's IP or by DNS. This is not *quite* the correct configuration but is close.
PCAP, you need to set up a SIP Trunk to your PEXIP node and then use an Outbound Rule to send calls destined for 75000 to that trunk. You don't need to use SIP registration, just point the trunk out to the node's IP. Ensure you have "PBX provides Audio" always turned off for endpoints and the trunk.
You might also consider sending a range of numbers out to PEXIP. If your VMRs are say 75000 to 75100 then route 75xxx out the trunk and skip users needing to enter their room ID.
Let me know if you need to see an example configuration. We do a lot of PEXIP and 3CX work and know that we've set this up before in our lab.