You're pretty much limited to the volume control on the phone. It may be that the trunk level, into the PBX is not as loud as it could be. Changing the volume (generally possible if trunks use a gateway) on trunking gets tricky, as there is a risk of introducing echo problems, if it is increases too much.
You might want to check that the the Codec that App is set to use, matches the one your trunks use so that there is no transcoding happening. That shouldn't make much of a difference, but always worth testing.